From my understanding. 91 legs before 135 legs count towards duty and flying limitations while 91 legs back home after the 135 legs don't count towards those limitation. The 91 leg has to be a flight back to your home base though.
I'm not sure if this is a contribution to the topic or my own ramblings to justify my understanding of the rules. Here goes;
So for example your beginning a trip that contains empty and revenue legs. The first two legs of the trip were flown empty as positioning legs (91) and the third leg will have customer stuff on board (revenue).
Even though the first two legs were flown empty, they were part of the assignment that includes a 135 revenue leg. The 135 flight/duty/rest rules apply to ALL of these legs since you will be carrying property/passengers on the final leg for revenue. As it was taught to me, "one drop poisons the whole well."
In the situations where you finish all of your 135 revenue flying and your company asks you to reposition to XYZ airport, you are legal to make these flights. Since the original trip has been completed and this new "tail end 91 leg" does not contain any 135 revenue legs, the 135 duty/rest/flight time rules do not apply.
Even if you just did your 8 hours and maxed out your 24 hour limitation, since these are not 135 revenue legs, that rule does not apply.
Since you are not flying a 135 revenue leg, you do not need your 10 consecutive hours of rest before starting that.
If your duty is at 14 hours upon completion of the trip, you can go off duty, duty back on and not be regulated by the 135 rest requirements because, you are not flying any 135 revenue legs.
To sum up what I'm trying to ramble here, Austin Collins says, "A flight with no customer property and no paying passengers on board may be conducted under Part 91. In that case, Part 135 regulations do not apply to that leg. If a duty assignment is scheduled to include even one Part 135 flight (leg), however, then §135.267 applies to the entire assignment in terms of whether you can accept it or not."
Here's the scenario.
You fly a pt91 flight, flying the owner in his airplane. Then, later that day, you have a charter book that will put you beyond your 135 duty time, due to the pt91 flight you did earlier in the day. Is this legal?
To try and answer the OP's question, the pt91 flight flying the owner in his own airplane needs to be clarified. Simply put, was it commercial flying? Also, were/should you have been on duty while doing that flight?
I'm not sure if the owner and his airplane are part of the same company/organization as the charter that you fly but if they are, then you should be on duty for those type of flights.
The flight time from that pt91 flight does count towards what you would be doing later that day with the charter if you were compensated for making that flight.
Hope this doesn't add to the confusion.