Better be upwind of it, even with SCBA on. While the actual firefighting portion is relatively the same as an aluminium aircraft in terms of toxic gases and such that you need to avoid, broken or burning composite materials release an untold number of carbon microfibers that can’t be seen, and which breathing of them can cause all kinds of respiratory problems, even some distance from the wreckage itself depending on winds, smoke plume, etc. This forces firefighters to be on theIr SCBA masks or some form of microfiber filter mask for much longer than just the firefighting portion of the work, but for rescue and salvage also, which not only gets extremely fatiguing, but is also inefficient in trying to do expedient rescue or search work, and results in materials such as SCBA bottles being used up much faster than normal. Which can be a problem if there isn’t an adequate supply or refill ability for these. That carbon fiber stuff is great structurally as an aircraft or car part, but it’s got some nasty drawbacks when broken/shredded/burning. Breathing in the particles has some serious ramifications to the lungs, both short and even long term.