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It is my personal feelings that as the Captain you should no longer worry about flying the airplane, doing the weight and balance, programming the FMS or getting tied down in details you can hand off to the FO. The Captain’s job is to MANAGE the aircraft, keep the big picture and make safe decisions.
Remember that with that responsibility you also need to know how to use your resources for the best and safest outcome of the flight. Even if it means admitting you are wrong or that someone else has a better idea. Which is sometimes the hardest thing for a new Captain to do even if it is the best thing. It was for me sometimes.
The crew, passengers, ATC, Dispatch, ramp and gate personnel are all responsible to the Captain. "The Pilot in Command of an aircraft is ultimately responsible for the safe conduct of the flight." (FAR 91.3). Or as Captain Len Morgan said "Everything in the FARs, the Policy Manual, your training, can all be summed up in one phrase: It's your call, Captain."
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“As the Captain, you never need to get upset or angry, or lose your temper. You have no need to explain in detail, any decision or request you make. You have already won any argument. You are the Captain".
"Remember, as an FO you could look to the left for advice. Now the only thing you are going to see when you look to the left is your own reflection in the window."