Waypoints that are strickly RNAV are 5 letters long and have to be phoneticly pronouncable (although there are some that aren't that easy). Ground based navigation stations (VORs, NDBs, LOCs etc) can be tuned in using a radio frequency and tracked that way, or for the most part also can be entered into a GPS/FMC using their letter identifier and become a fix in the RNAV world. As far as pure GPS fixes used for enroute flight? I don't think you will find too many on victor or jet airways as they need to be navigatble by /a aircraft, although now that I think about there are some (fixes that are marked by an "x" on a jep chart). Also in the enroute stage it is pretty common to be cleared direct to a VOR when you are too far to pick it up. For RNAV aircraft it is a simple matter of throwing the identifier in the box and pressing NAV. The /a airplanes will generally ask for a heading and get a response like "fly 040, direct XXX when able." Is that what you were asking?