I've been flying an Aztec quite a bit lately - here's what I do.
I switch back and forth every hour, starting with the outboards. With the way I run the engines, I plan on being on the ground after 4 hours max, so it's easy to keep track from a timing standpoint.
Here's the best trick: get a Westbend timer clock that can run 2 SIMULTANEOUS TIMERS at once. Put it on a yoke clip right in front of you. Use #1 timer for the left tank (or in the Aztec's case, outboards) and #2 timer for the right tank (inboards). Start and stop each timer as you use fuel from each tank, so you always have a running tally of how much time/fuel you have used from each tank at any given point during the flight. Plus, if you land someplace you can just stop the timer, then re-start it when you fire up again if you don't top the tanks.
This timing system has worked in the Aztec and the old style Cessna 206's (no "both" selector position, just L and R) that I have been flying for the last year or so.
One thing I would NEVER recommend is using one tank from takeoff until it's almost empty, then switching tanks. Why? What if you have an inflight fuel selector valve malfunction, making it impossible to switch to a different tank. Now you've screwed yourself; you've drained your only usable tank and you may not have enough gas left to divert someplace. I recommend a switching system that will leave you enough fuel in your active tank, at any given time, to confidently divert and land. Alternatively, you can test your fuel selector valve early in the flight to verify that it is working properly.
There is an interesting story behind this last recommendation (a "close call" situation involving myself and another pilot) but I won't get into that now...to protect the innnocent