Im gonna just kinda reiterate what has already been said: Its all about who you know. I just got hired by a charter company in southern california to fly the CE-550...Im currently just a flight instructor.
I just happened to in the flight school office when a guy came in and wanted to use our FTD for instrument currency. None of the other instructors wanted to help the guy out, so i said what the heck and spent an hour or so in the sim with him. Turns out he was the assitant chief pilot for a charter company and he wanted to get a couple hours in the sim before going to simuflight for his G-II type rating. About an hour after we were done with the sim, he calls me up and asks if im looking for a job and that I should come in and meet the owners of the company he works for... if I would have shunned the guy off like the other instructors, I would have never had this oppertunity.
You just never know how or when your gonna meet the right people, but thats really what it comes down to in this biz.