However, exactly as you noted, there isn't a practical application for using either minimum sink speed or best glide speed in a steep spiral maneuver.
By definition, the steep spiral will be at a speed above best glide or minimum sink. Otherwise it would simply be a steep turn.
In airplanes, the purpose of a steep spiral is to intentionally lose altitude in a minimum radius turn over a fixed point. It is done at a specified speed that will give sufficient sink.
In gliders, the spiral dive happens when the nose is too low in a steep turn, typically in a thermal. The glider will build excessive airspeed and sink, and the wings are not sufficiently loaded, resulting in the airspeed buildup.
In both cases, the recovery is to level the wings in a coordinated fashion, and then pitch up to slow the aircraft. (It is entirely possible to overstress the airframe trying to slow it to best glide/min sink first, which is why the wings should be levelled first.)
But to answer the original question, best glide (and more appropriately minimum sink) both increase in a bank. For a typical training glider with MCA at 35kts, thermalling at 60 deg bank the MCA would then be 50kts.
One more thing - in a steep bank, not all aircraft have sufficient elevator authority to stall past 60 degrees of bank. This is true of almost all gliders - past 60 degrees bank, with full back stick, airspeed will increase as the nose drops, resulting in a spiral dive. This is the primary reason that gliders tend to fly a tighter traffic pattern with much steeper bank than airplanes do.