Avgas and Jet A are different colors, though there's a good chance the blue dye in the 100LL would dye the JetA blue as well. They smell a lot different, and if you get them on your hands you know immediately which one is which.
In the video he states that he had them top off the tip tanks. If the wing tanks still had avgas in them, he probably could have just switched tanks. When an engine quits, it's almost always fuel.